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Floating Potential

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I have a question about floating potential condition. I have 2 metals (like electrodes) which are not directly connected to voltage source and i want to use them to measure the signal (or voltage variation in my medium). According to some of the posts here i should use floating potential option as my boundary conditions for these metals. Is that right?
And if it is correct, then what should i assign in its terminal charge value section (in floating potential option)?

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Bahareh

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